C2 Radical (C2) - LIF:

Transitions: Swan bands: d 3Pg <--> a 3Pu (2,0), (3,1), (4,2) bands (excitation wavelength: about 438,0 nm to 408,0 nm)

             Deslandres-d'Azambuja bands: C 1Pg <--> A 1Pu (0,2), (1,3) bands (excitation wavelength: about 438 nm to 410 nm)

             Mulliken bands: D 1Su+ <--> X 1Sg+ (1,0), (2,1), (3,2) bands (excitation wavelength: about 225 nm to 218 nm)

             Mulliken bands: D 1Su+ <--> X 1Sg+ (2,0), (3,1), (4,2) bands (excitation wavelength: about 217 nm to 212 nm)

             Freymark bands: E 1Sg+ < --> A 1Pu (0,1), (1,2), (2,3)  bands (excitation wavelength: about 224 nm to 216 nm)

             Freymark bands: E 1Sg+ < --> A 1Pu (0,0), (1,1), (2,2)  bands (excitation wavelength: about 214 nm to 210 nm)

Appearance of the C2 transitions: Swan bands: Degraded to the violet

                                    Deslandres- d'Azambuja bands: Degraded to the violet

                                    Mulliken bands: ?

                                    Freymark bands: Degraded to the violet

Excitation wavelength: 450,0 to 419,2 nm (VIS) and 225,0 to 209,6 nm (UV)

Flame/Burner: acetylene/oxygen (C2H2/O2) flame of a welding torch

Grating of the spectrograph: 1200 l/mm

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Grating: 1200 lines/mm, only VIS excitation, Emissions: 330 to 365 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   330 nm to 365 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 430,32 nm

Detected signals:

   C2-LIF C-A / from C-A (1,3), (2,4) ... excitations:

      (Deslandres-d'Azambuja bands, starting at 434,0 nm)

   C2-LIF / Deslandres d'Azambuja band emissions:

      (339 nm, 360 nm)

   CN-LIF B-X / from B-X (1,2) excitation:

      (starting at 419,9 nm (1,2))

   CN-LIF / B-X emissions:

      (358 nm)

   broadband fluorescence of hydrocarbon species:

      (emission wavelength: about 300 nm to 450 nm )

   (no signals detected in the off-center range of the flame) 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,4 to 24,3 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 365 to 400 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   365 nm to 400 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 438,00 nm

Detected signals:

   C2-LIF C-A / from C-A (0,2), (1,3) ... excitations:

      (Deslandres-d'Azambuja bands, starting at 438,0 nm)

   C2-LIF / Deslandres d'Azambuja band emissions:

      (385 nm)

   CN-LIF B-X / from B-X (0,1) and (1,2) excitations:

      (starting at 421,6 nm (0,1) and  419,9 nm (1,2))

   CN-LIF / B-X emissions:

      (388 nm)

   broadband fluorescence of hydrocarbon species:

      (emission wavelength: about 300 nm to 450 nm)

   (no signals detected in the off-center range of the flame) 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,4 to 23,8 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 400 to 435 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   400 nm to 435 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 433,60 nm

Detected signals:

   Rayleigh scattering: VIS

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (438 nm)

    C2-LIF C-A / from C-A (0,2), (1,3) ... excitations:

      (Deslandres-d'Azambuja bands, starting at 438,0 nm)

   C2-LIF / Deslandres d'Azambuja band emissions:

      (410 nm, 438 nm)

   CN-LIF B-X / from B-X (0,1) and (1,2) excitations:

      (starting at 421,6 nm (0,1) and  419,9 nm (1,2))

   CN-LIF / B-X emissions:

      (421 nm)

   broadband fluorescence of hydrocarbon species:

      (emission wavelength: about 300 nm to 450 nm)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,6 to 23,6 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 420 to 455 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   420 nm to 455 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 437,20 nm

Detected signals:

   Rayleigh scattering: VIS

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (438 nm)

    C2-LIF C-A / from C-A (0,2), (1,3) ... excitations:

      (Deslandres-d'Azambuja bands, starting at 438,0 nm)

   C2-LIF / Deslandres d'Azambuja band emissions:

      (438 nm)

   CN-LIF B-X / from B-X (0,1) excitation:

      (starting at 421,6 nm (0,1))

   CN-LIF / B-X emissions:

      (421 nm)

   broadband fluorescence of hydrocarbon species:

      (emission wavelength: about 300 nm to 450 nm)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,1 to 25,0 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 455 to 490 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   455 nm to 490 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 437,20 nm

Detected signals:

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (starting at 473 nm)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 26,1 to 22,5 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 490 to 525 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   490 nm to 525 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 438,00 nm

Detected signals:

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (starting at 516 nm (0,0) band)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 26,1 to 22,5 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 525 to 560 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   525 nm to 560 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 437,20 nm

Detected signals:

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (starting at 563 nm (0,1) band)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,0 to 22,2 mJ/pulse

   

Grating: 1200 lines/mm, only VIS excitation, Emissions: 575 to 610 nm

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  no UV excitation

   VIS: 440,00 nm to 419,24 nm

Emission wavelength:

   575 nm to 610 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: no UV excitation

   VIS: 436,40 nm

Detected signals:

   C2-LIF d-a / from d-a (2,0), (3,1), (4,2) ... excitations:

      (Swan bands, starting at 438,0 nm)

   C2-LIF / Swan band emissions:

      (starting at 606 nm (2,4) band)

   (no signals detected in the off-center range of the flame) 

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 8,3 / entrance slit: 50 mm / sum of pulses: 50 /

VIS pulse energy: about 27,8 to 24,3 mJ/pulse

   

Grating: 1200 lines/mm, UV and VIS excitation, Emissions: 195 to 230 nm, part 1

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  227,00 nm to 215,50 nm

   VIS: 454,00 nm to 431,00 nm

   (UV and VIS simultaneously)

Emission wavelength:

   195 nm to 230 nm

EES, point of measurement:

    off-center  (outer range of the flame)

Excitation wavelength:

   UV: 227,00 nm to 215,50 nm

   VIS: 454,00 nm to 431,00 nm

   (UV and VIS simultaneously)

Emission wavelength:

   195 nm to 230 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: 220,98 nm

   VIS: 441,96 nm

   (UV and VIS simultaneously)

Detected signals:

   Rayleigh scattering: UV

   C2-LIF D-X / from D-X (1,0), (2,1) ... excitations:

      (Mulliken bands, starting at about 225 nm)

   C2-LIF / Mulliken band emissions:

      (starting at about 222 nm)

   C2-LIF E-A / from E-A (0,2), (1,3) ... excitations:

      (Freymark bands, starting at about 229,7 nm)

   C2-LIF / Freymark band emissions:

      (starting at: 222 nm, 214 nm, 207 nm)

   C2-LIF E-A / from E-A (0,1), (1,2) ... excitations:

      (Freymark bands, starting at about 221,8 nm)

   C2-LIF / Freymark band emissions:

      (starting at: 222 nm, 214 nm, 207 nm)

   NO-LIF A-X / from  A-X (0,0) and (1,1) excitation (weak):

      (starting at 226,8 nm (0,0) and 224,4 nm (1,1))

   NO-LIF A-X emissions:

      (starting at: 227 nm, 215 nm)

Detected signals:

   Rayleigh scattering: UV

   NO-LIF A-X / from  A-X (0,0), (1,1), (2,2)...  excitations:

      (starting at 226,8 nm (0,0), 224,4 nm (1,1), 222,2 nm (2,2))

   NO-LIF A-X emissions:

      (starting at: 227 nm, 215 nm, 205 nm)

 

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CCD dynamic: 12 bit / ICCD gain: 9,3 / entrance slit: 80 mm / sum of pulses: 50 /

VIS pulse energy: about 2,85 to 2,60 mJ/pulse

   

Grating: 1200 lines/mm, UV and VIS excitation, Emissions: 190 to 225 nm, part 2

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  215,70 nm to 209,72 nm

   VIS: 431,40 nm to 419,44 nm

   (UV and VIS simultaneously)

Emission wavelength:

   190 nm to 225 nm

EES, point of measurement:

    off-center  (outer range of the flame)

Excitation wavelength:

   UV: 215,70 nm to 209,72 nm

   VIS: 431,40 nm to 419,44 nm

   (UV and VIS simultaneously)

Emission wavelength:

   190 nm to 225 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: 214,14 nm

   VIS: 428,28 nm

   (UV and VIS simultaneously)

Detected signals:

   Rayleigh scattering: UV

   C2-LIF E-A / from E-A (0,0), (1,1) ... excitations:

      (Freymark bands, starting at about 214,3 nm)

   C2-LIF / Freymark band emissions:

      (starting at: 222 nm, 214 nm, 207 nm)

   NO-LIF A-X / from  A-X (1,0) excitation (weak):

      (starting at 215,3 nm (1,0))

   NO-LIF A-X emissions:

      (starting at: 225 nm, 215 nm)

Detected signals:

   Rayleigh scattering: UV

   NO-LIF A-X / from  A-X (1,0), (2,1), (3,2) excitations:

      (starting at 215,3 nm (1,0), 214,0 nm (2,1))

   NO-LIF A-X emissions:

      (starting at: 225 nm, 215 nm, 205 nm, 196 nm)

   hot O2-LIF

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CCD dynamic: 12 bit / ICCD gain: 9,0 / entrance slit: 100 mm / sum of pulses: 50 /

VIS pulse energy: about 2,6 to 1,6 mJ/pulse

   

Grating: 1200 lines/mm, UV and VIS excitation, Emissions: 230 to 265 nm, part 1

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV: 227,00 nm to 215,50 nm

   VIS: 454,00 nm to 431,00 nm

   (UV and VIS simultaneously)

Emission wavelength:

   230 nm to 265 nm

EES, point of measurement:

    off-center  (outer range of the flame)

Excitation wavelength:

   UV: 227,00 nm to 215,50 nm

   VIS: 454,00 nm to 431,00 nm

   (UV and VIS simultaneously)

Emission wavelength:

   230 nm to 265 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: 222,28 nm

   VIS: 444,56 nm

   (UV and VIS simultaneously)

Detected signals:

   C2-LIF D-X / from D-X (1,0), (2,1) ... excitations:

      (Mulliken bands, starting at about 225 nm)

   C2-LIF / Mulliken band emissions:

      (231 nm)

  C2-LIF D-X / from D-X (2,0), (3,1) ... excitations:

      (Mulliken bands, starting at about 217 nm)

   C2-LIF / Mulliken band emissions:

      (231 nm)

   C2-LIF E-A / from E-A (0,1), (1,2) ... excitations:

      (Freymark bands, starting at about 221,8 nm)

   C2-LIF / Freymark band emissions:

      (starting at 230 nm)

   NO-LIF A-X / from  A-X (0,0) excitation:

      (starting at 226,8 nm (0,0))

   NO-LIF A-X emissions:

      (starting at: 259 nm, 248 nm, 237 nm)

Detected signals:

   NO-LIF A-X / from  A-X (0,0), (1,1) excitations:

      (starting at 226,8 nm (0,0))

   NO-LIF A-X emissions:

      (starting at: 259 nm, 248 nm, 237 nm)

   hot O2-LIF (weak)

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CCD dynamic: 12 bit / ICCD gain: 9,3 / entrance slit: 80 mm / sum of pulses: 50 /

VIS pulse energy: about 3,10  to 3,42 mJ/pulse

   

Grating: 1200 lines/mm, UV and VIS excitation, Emissions: 225 to 260 nm, part 2

EES, point of measurement:

   center (inner cone of the flame)

Excitation wavelength:

   UV:  215,70 nm to 209,72 nm

   VIS: 431,40 nm to 419,44 nm

   (UV and VIS simultaneously)

Emission wavelength:

   225 nm to 260 nm

EES, point of measurement:

    off-center  (outer range of the flame)

Excitation wavelength:

   UV: 215,70 nm to 209,72 nm

   VIS: 431,40 nm to 419,44 nm

   (UV and VIS simultaneously)

Emission wavelength:

   225 nm to 260 nm

Single Image:

   local distribution of signals inside the flame

Excitation wavelength:

   UV: 214,16 nm

   VIS: 428,32 nm

   (UV and VIS simultaneously)

Detected signals:

   C2-LIF D-X / from D-X (2,0), (3,1) ... excitations:

      (Mulliken bands, starting at about 217 nm)

   C2-LIF / Mulliken band emissions:

      ( 231 nm)

   C2-LIF E-A / from E-A (0,0), (1,1) ... excitations:

      (Freymark bands, starting at about 214,3 nm)

   C2-LIF / Freymark band emissions:

      (238 nm, 229,7 nm)

   NO-LIF A-X /from A-X (1,0) excitation

Detected signals:

  NO-LIF A-X / from  A-X (1,0), (2,1), (3,2) excitations:

      (starting at 215,3 nm (1,0), 214,0 nm (2,1))

   NO-LIF A-X emissions:

(starting at: 256 nm (259 nm), 245 nm (248 nm), 234 nm (237 nm), 225 nm (227 nm))

   hot O2-LIF (weak)

Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: 

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CCD dynamic: 12 bit / ICCD gain: 9,0 / entrance slit: 100 mm / sum of pulses: 50 /

VIS pulse energy: about 3,42 to 2,02 mJ/pulse

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