Hot Molecular Oxygen (O2) - LIF:
Transition: Schumann-Runge bands: B3Su- - X3Sg- (0,7), (0,8), (0,9), (1,8), (1,9), (2,8), (2,9), (2,10), ... bands of hot molecular oxygen O2 (excitation wavelengths: see table below)
Appearance of the Schumann-Runge system: Degraded to the red
Excitation wavelength: 278,5 to 259,0 nm (UV)
Flame/Burner: hydrogen/oxygen (H2/O) flame of a welding torch
Grating of the spectrograph: 100 l/mm
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Table: Expected transitions/emissions (Herzberg, 1979)
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Transitions of O2 Schumann-Runge bands |
Excitation wavelength range [nm] |
Emissions [nm] starting at: |
| B-X (0,9) band starting at 276,4 nm | 276,4 nm deg. to the red | 202,6 nm, 209,2 nm, 216,1 nm, 223,4 nm, 231,1 nm, 239,2 nm, 247,7 nm, 256,7 nm, 266,3 nm, 276,4 nm, 287,1 nm, 298,4 nm, 310,5 nm, 323,4 nm, 337,1 nm, 351,8 nm, ... |
| B-X (2,10) band starting at 276,3 nm | 276,3 nm deg. to the red | 197,2 nm, 203,4 nm, 210,0 nm, 216,9 nm, 224,1 nm, 231,7 nm, 239,7 nm, 248,1 nm, 257,0 nm, 266,4 nm, 276,3 nm, 286,9 nm, 298,0 nm, 309,8 nm, 322,4 nm, 335,8 nm, … |
| B-X (3,10) band starting at 271,5 nm | 271,5 nm deg. to the red | 194,7 nm, 200,8 nm, 207,2 nm, 213,9 nm, 220,9 nm, 228,3 nm, 236,1 nm, 244,2 nm, 252,8 nm, 261,9 nm, 271,5 nm, 281,7 nm, 292,4 nm, 303,8 nm, 315,9 nm, 328,7 nm, … |
| B-X (1,9) band starting at 271,2 nm | 271,2 nm deg. to the red | 199,8 nm, 206,2 nm, 213,0 nm, 220,0 nm, 227,5 nm, 235,3 nm, 243,6 nm, 252,3 nm, 261,5 nm, 271,2 nm, 281,5 nm, 292,4 nm, 304,0 nm, 316,4 nm, 329,5 nm, 343,5 nm, … |
| B-X (2,9) band starting at 266,4 nm | 266,4 nm deg. to the red | 197,2 nm, 203,4 nm, 210,0 nm, 216,9 nm, 224,1 nm, 231,7 nm, 239,7 nm, 248,1 nm, 257,0 nm, 266,4 nm, 276,3 nm, 286,9 nm, 298,0 nm, 309,8 nm, 322,4 nm, 335,8 nm, … |
| B-X (0,8) band starting at 266,3 nm | 266,3 nm deg. to the red | 202,6 nm, 209,2 nm, 216,1 nm, 223,4 nm, 231,1 nm, 239,2 nm, 247,7 nm, 256,7 nm, 266,3 nm, 276,4 nm, 287,1 nm, 298,4 nm, 310,5 nm, 323,4 nm, 337,1 nm, 351,8 nm, ... |
| B-X (3,9) band starting at 261,9 nm | 261,9 nm deg. to the red | 194,7 nm, 200,8 nm, 207,2 nm, 213,9 nm, 220,9 nm, 228,3 nm, 236,1 nm, 244,2 nm, 252,8 nm, 261,9 nm, 271,5 nm, 281,7 nm, 292,4 nm, 303,8 nm, 315,9 nm, 328,7 nm, … |
| B-X (1,8) band starting at 261,5 nm | 261,5 nm deg. to the red | 199,8 nm, 206,2 nm, 213,0 nm, 220,0 nm, 227,5 nm, 235,3 nm, 243,6 nm, 252,3 nm, 261,5 nm, 271,2 nm, 281,5 nm, 292,4 nm, 304,0 nm, 316,4 nm, 329,5 nm, 343,5 nm, … |
| B-X (2,8) band starting at 257,0 nm | 257,0 nm deg. to the red | 197,2 nm, 203,4 nm, 210,0 nm, 216,9 nm, 224,1 nm, 231,7 nm, 239,7 nm, 248,1 nm, 257,0 nm, 266,4 nm, 276,3 nm, 286,9 nm, 298,0 nm, 309,8 nm, 322,4 nm, 335,8 nm, … |
| B-X (0,7) band starting at 256,7 nm | 256,7 nm deg. to the red | 202,6 nm, 209,2 nm, 216,1 nm, 223,4 nm, 231,1 nm, 239,2 nm, 247,7 nm, 256,7 nm, 266,3 nm, 276,4 nm, 287,1 nm, 298,4 nm, 310,5 nm, 323,4 nm, 337,1 nm, 351,8 nm, ... |
Grating: 100 lines/mm, UV and VIS excitation, Emissions: 190 to 605 nm, part 1
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EES, point of measurement: center (center of the flame) Excitation wavelength: UV: 278,35 nm to 274,00 nm VIS: 556,70 nm to 548,00 nm (UV and VIS simultaneously) Emission wavelength: 190 nm to 605 nm |
Single Image: local distribution of signals inside the flame Excitation wavelength: UV: 274,33 nm VIS: 548,66 nm (UV and VIS simultaneously) |
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Detected signals: Rayleigh scattering: UV and VIS hot O2-LIF from Schumann-Runge bands: (for more information see table on top of this page) OH-LIF A-X / from A-X (2,0) and (3,1) excitations: (starting at: 259,2 nm (2,0)) OH-LIF A-X emissions: (278 - 302 nm, 302 - 335 nm) Rayleigh and OH-LIF in 2nd order |
Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: |
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Download
Davis file: |
CCD dynamic: 12 bit / ICCD gain: 9,9 / entrance slit: 80 mm / sum of pulses: 50 / UV pulse energy: about 2,65 to ... mJ/pulse |
Grating: 100 lines/mm, UV and VIS excitation, Emissions: 190 to 605 nm, part 2
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EES, point of measurement: center (center of the flame) Excitation wavelength: UV: 274,50 nm to 256,00 nm VIS: 549,00 nm to 512,00 nm (UV and VIS simultaneously) Emission wavelength: 190 nm to 605 nm |
Single Image: local distribution of signals inside the flame Excitation wavelength: UV: 260,70 nm VIS: 521,40 nm (UV and VIS simultaneously) |
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Detected signals: Rayleigh scattering: UV and VIS hot O2-LIF from Schumann-Runge bands: (for more information see table on top of this page) OH-LIF A-X / from A-X (2,0) and (3,1) excitations: (starting at: 259,2 nm (2,0) and 267,5 nm (3,1)) OH-LIF A-X emissions: (259 - 275 nm, 278 - 302 nm, 302 - 335 nm, 340 - 360 nm, 405 nm) NO-LIF A-X / from A-X (0,3) excitation: (starting at 259,5 nm (0,3)) NO-LIF A-X emissions: (272 nm, 260 nm, 248 nm, 237 nm, 227 nm) Rayleigh, O2-LIF, NO-LIF and OH-LIF in 2nd order |
Download common measurement report for detailed informations about flame, laser beam position, pulse energy, ICCD gain, etc: |
|
Download
Davis file: |
CCD dynamic: 12 bit / ICCD gain: 8,6 / entrance slit: 80 mm / sum of pulses: 50 / UV pulse energy: about 3,1 to 3,5 mJ/pulse |